سنتز نانو ذرات اکسید فلزی مس - قلع به روش انفجار الکتریکی سیم و بررسی خواص ضد باکتری آن

فصلنامه علمی - پژوهشی مواد نوین

مقاله 10، دوره 8، شماره 32، مرداد 1397، صفحه 125-136   

نوع مقاله: مقاله پژوهشی

نویسندگان

داود یارعلی¹؛ رضا احمدی^{* 2}؛ رامین حسینی³

¹دانشجوی کارشناسی ارشد مهندسی مواد، دانشکده فنی مهندسی، دانشگاه بین المللی امام خمینی (ره)، قزوین، ایران

²استادیار، دانشکده فنی و مهندسی، گروه مواد وسرامیک، دانشگاه بین المللی امام خمینی (ره)، قزوین، ایران

³دانشیار، دانشکده فنی و مهندسی، گروه مهندسی بیوتکنولوژی، دانشگاه بین المللی امام خمینی (ره)، قزوین، ایران

تاریخ دریافت: 29 تیر 1396،  تاریخ بازنگری: 21 مرداد 1397،  تاریخ پذیرش: 02 دی 1396 

چکیده

    به دلیل خواص فیزیکی- شیمیایی منحصر به فرد نانو ذرات در مهار رشد باکتری، پژوهش بر روی نانو ذرات و کاربردهایشان به عنوان عامل ضد میکروبی افزایش یافته است. در این بررسی نانو ذرات مس- قلع و اکسیدهای آن به روش انفجار الکتریکی در محیط آب بین الکترودهای مس- قلع سنتز شد. این روش امکان تهیه نانو ذرات اکسیدی و فلزی با نرخ تولید بالا و فعالیت سطحی زیاد را فراهم می­آورد. نانو ذرات اکسید مس و اکسید قلع به عنوان نانو ذرات کاربردی با فعالیت ضد باکتری موثر شناخته شده­اند. مشخصه­یابی نانو ذرات ساخته شده با استفاده از تکنیک پراش پرتو ایکس، طیف سنج مرئی- فرابنفش، میکروسکوپ الکترونی روبشی و آنالیز BET  انجام شد. نتایج  نشان داد با تغییر شدت جریان اعمالی، نانوذرات اکسید مس - قلع با اندازه میانگین حدود ۱۹ تا 5/37 نانومتر به روش انفجار الکتریکی سیم تشکیل شدند. فعالیت ضد باکتری نانوذرات در برابر باکتری اشرشیاکولی با استفاده از غلظت­های مختلف نمونه­های نانو ذرات اکسید مس- قلع  به روش تعیین چگالی نوری مورد بررسی قرار گرفت. نتایج نشان دادند که نانو ذرات اکسید مس- قلع دارای خاصیت ضد باکتری هستند و این خاصیت با افزایش غلظت نانو ذره در محیط مایع و کاهش متوسط اندازه دانه، افزایش می­یابد.

کلیدواژه‌ها

انفجار الکتریکی سیم؛ نانو ذره؛ اکسید مس - قلع؛ آنتی ‌باکتریال

عنوان مقاله [English]

Synthesis of copper-tin metal oxide nanoparticles by the electrical explosion wire method and investigation antibacterial properties

نویسندگان [English]

D. Yarali¹؛ R. Ahmadi²؛ R. Hosseini³

¹Student Materials Engineering - Identification and Selection of Engineering Materials , Imam Khomeini University of Qazvin - Iran

²-Department of Materials Engineering, Imam Khomeini International University, Qazvin, Iran

³Department of Biotechnology, Faculty of Agriculture and Natural Resources, Imam Khomeini University, Qazvin, Iran

چکیده [English]

     Due to the unique physicochemical properties of nanoparticles with the ability to inhibit the growth of bacteria, research has increased on nanoparticles and their applications as the antimicrobial agents. In this study, nanoparticles of copper - tin oxide were synthesized via
electrical explosion in water between copper-tin electrodes. This method provides the possibility of producing oxide and metal nanoparticles with high production rates and high surface activity. Copper oxide and tin oxide nanoparticles are known as practical nanoparticles with antibacterial activity. Nanoparticles characterization was performed using the X-ray diffraction, scanning electron microscopy, UV-visible absorption recording and BET analysis. The results showed that by changing the intensity of the applied current, oxide copper - tin with an average size of about 19 to 37.5 nm were formed by electrical explosion of wire. Antibacterial activity of nanoparticles against the E. coli bacteria was evaluated by determining the optical density of various samples with different concentrations of tin and copper oxide nanoparticles. The results showed that the copper - tin oxide nanoparticles possess antibacterial properties and this activity enhances by increasing the concentration of nanoparticles in the liquid medium and reduction the average grain size.

کلیدواژه‌ها [English]

Electrical explosion of wire, Nanoparticles, Copper – tin oxide, Antibacterial

مراجع

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