Synthesizing and Characterization of Monoclinic and Tetragonal Phases of Zirconium Oxide (Zro2) Nanofibers with the Aid of Electrospinning Technique

Journal of Optoelectronical Nanostructures

مقاله 4، دوره 5، شماره 2 - شماره پیاپی 18، مرداد 2020، صفحه 39-48   

نوع مقاله: Articles

نویسندگان

Yaser Zarea^{* 1}؛ Saeed Parhoodeh²؛ Leila Shahryari³؛ Ali Karbakhsh³

¹Civil Engineering Department, Islamic Azad University, Sirjan Branch, Sirjan, Iran

²Physics Department, Islamic Azad University, Shiraz Branch, Shiraz, Iran

³Civil Engineering Department, Islamic Azad University, Shiraz Branch, Shiraz, Iran

تاریخ دریافت: 07 اسفند 1398،  تاریخ پذیرش: 14 اردیبهشت 1399 

چکیده

Zirconium oxide has found extensive applications in various industries because
of its excellent properties such as high strength; high-temperature resistance;
extraordinary wearing resistance; ionic conductivity; and corrosion resistance. Also, some
Properties like high melting point, high mechanical and thermal strength, high dielectric
constant and low conductivity have introduced this material as a prominent candidate for
engineering applications. In this study, zirconium oxide (ZrO2) Nano fibers was
synthesized by calcination of propoxide zirconium oxide/polyvinyl alcohol using sol-gel
and electrospinning methods. The morphology of the Nano fibers was verified by
scanning electron microscopy (SEM) and its crystalline phase was investigated by x-ray
diffraction and energy-dispersive x-ray spectroscopy (EDS). The mean diameter of the
Nano fibers varied in the range of 70-200 nm. XRD patterns also indicated the presence
of monoclinic and tetragonal phases in the Nano fibers calcined at 700 ℃. Results also
revealed that this new precursor can be used in the electrospinning technique to obtain
ZrO2 Nano fibers with relatively high purity.

کلیدواژه‌ها

Zirconium Oxide Nano Fiber؛ Electrospinning؛ Scanning Electron Microscope (SEM)؛ X-Ray Diffraction (XRD)؛ Energy-Dispersive XRay Spectroscopy (EDS)

سایر فایل های مرتبط با مقاله

39-48 Yaser Zarea.pdf

مراجع

[1]
Y. Liu and C. Wang, Advanced Nanofibrous Materials Manufacture Technology Based on Electrospinning, Vols. CRC Press: Boca Raton, FL, USA, (2019), 370.
[2]
L. Haodong, B. Jinxiao, Q. Siyu, J. Qiang and G. Wenrong, Optical and mechanical properties of purplezirconia ceramics, Journal of Asian Ceramic Societies, 7 (3), (2019), 306-311.
[3]
O. Mangla and S. Roy, Monoclinic Zirconium Oxide Nanostructures Having Tunable Band Gap Synthesized under Extremely Non-Equilibrium Plasma Conditions, Proceedings, 3, 10, (2019), 1-7.
Synthesizing and characterization of monoclinic and tetragonal phases of Zirconium … * 45
[4]
E. Bَdisa, K. Molnلr, A. Mucsi, Z. Kلroly, J. Mَczَ, S. Klébert, A. M. Keszler, P. Fazekas and J. S. Szépvِlgyi, Silicon nitride-based composites reinforced with Zirconia nanofiber, Ceram. Int., Vol. 43, (2017), 16811–16818.
[5]
J. Koo, Y. Lim, Y. Kim, D. Byun, W. Lee, Electrospun yttria-stabilized Zirconia nanofibers for low-temperature solid oxide fuel cells, Int. J. Hydrogen Energy, Vol. 42, (2017), 15903–15907.
[6]
V. V. Rodaev, S. S. Razlivalova, A. I. Tyurin, A. O. Zhigachev and Y. I. Golovin, Microstructure and Phase Composition of Yttria-Stabilized Zirconia Nanofibers Prepared by High-Temperature Calcination of Electrospun Zirconium Acetylacetonate/Yttrium Nitrate/Polyacrylonitrile Fibers, Fibers, 7 (82), (2019), 1-8.
[7]
T. Xue-Yu, . M. Jie, H. Rui-Lin, S. Xiang-Zhu, G. Lin, Z. Shi-Xiang, G. Li-Tong, L. Zhang-Sheng, F. He-Liang and Z. Ya-Bo, Template-Free Synthesis of Star-Like ZrO2 Nanostructures and Their Application in Photocatalysis, Advances in Materials Science and Engineering, (2018), 1-10.
[8]
N. Yazdani, J. Javadpour, Y. Eftekhari and M. Hamrang, Hydrothermal Synthesis of Cobalt- Doped Hydroxyapatite Nanoparticles: Structure, Magnetic Behavior, Bioactivity and Antibacterial Activity, Iranian Journal of Materials Science & Engineering, 16 (1), (2019), 39-48.
[9]
M. C. U. Lَpez, M. A. A. Lemus, M. C. Hidalgo, R. Lَpez Gonzلlez, P. Q. Owen, S. O. Ruiz, S. A. U. Lَpez and J. Acosta, Synthesis and Characterization of ZnO-ZrO2 Nanocomposites for Photocatalytic Degradation and Mineralization of Phenol, Journal of Nanomaterials, (2019), 1-9.
[10]
A. P. Ayanwale, A. D. Cornejo, J. C. C. Gonzلlez, L. F. E. Cristَbal and S. Y. R. Lَpez, REVIEW OF THE SYNTHESIS, CHARACTERIZATION AND APPLICATION OF ZIRCONIA MIXED METAL OXIDE
46 * Journal of Optoelectronical Nanostructures Spring 2020 / Vol. 5, No. 2
NANOPARTICLES, International Journal of Research GRANTHAALAYAH, vol. 6, no. 8, (2018), 136-145.
[11]
M. Baek, S. Park and D. Choi, Synthesis of Zirconia (ZrO2) nanowires via chemical vapor deposition, Journal of Crystal Growth, vol. 459, (2017), 198-202.
[12]
A. S. Keiteb, E. Saion, A. Zakaria and N. Soltani, Structural and Optical Properties of Zirconia Nanoparticles by Thermal Treatment Synthesis, Journal of nanomaterials, (2016), 1-6.
[13]
V. V. Rodaev, S. S. Razlivalova, A. O. Zhigachev, V. M. Vasyukov and Y. I. Golovin, Preparation of Zirconia Nanofibers by Electrospinning and Calcination with Zirconium Acetylacetonate as Precursor, Polymers, vol. 11, (2019), 1067.
[14]
Y. Zhoua, W. Songa, L. Zhanga and S. Tao, Preparation of Hollow Magnetic Porous Zirconia Fibers as Effective Catalyst Carriers for Fenton Reaction, Journal of Materials Chemistry A, vol. 6, (2018), 12298-12307.
[15]
G. -X. Sun, L. Fu-Tian, J. Qiang and C. -A. Wang, Electrospun Zirconia nanofibers and corresponding formation mechanism study, Journal of Alloys and Compounds, vol. 649, (2015), 788–792.
[16]
P. Murugavel, M. Kalaiselvam, A. R. Raju and C. N. R. Rao, Sub-micrometre spherical particles of TiO2, ZrO2 and PZT by nebulized spray pyrolysis of metal-organic precursors, Journal of Materials Chemistry, Vol. 7, No. 8, (2015), 1433–1438.
[17]
S. Hassan, M. Elkady and H. Hamad, Synthesis and Characterization of Stabilized Tetragonal Nano Zirconia by Precipitation Method, Journal of Nano Research, Vol. 56, (2019), 142-151.
[18]
S. Y. Ahmed, M. Obaid, M. M. Ibrahim, Y. Ahmed and N. A. M. Barakat, ZrO2 nanofibers/activated carbon composite as a novel and effective
Synthesizing and characterization of monoclinic and tetragonal phases of Zirconium … * 47
electrode material for the enhancement of capacitive deionization performance, RSCAdvances, vol. 7, (2017), 4616-4626.
[19]
O. Saligheh, R. Khajavi, M. E. Yazdanshenas and A. Rashidi, Production and Characterization of Zirconia (ZrO2) Ceramic Nanofibers by Using Electrospun Poly(Vinyl Alcohol)/Zirconium Acetate Nanofibers as a Precursor, JOURNAL OF MACROMOLECULAR SCIENCE, Vol. 55, No. 6, (2016), 605–616.
[20]
R. Ghelich, R. Mehdinavaz Aghdam, F. s. Torknik and M. R. Jahannama, Synthesis and characterization of biocompatible Zirconia nanofibers based on electrospun PVP/Zr(OPr)4, Materials Today: Proceedings 5, (2018), 5733–15738.
[21]
Saeed Parhoodeh, Mohammad Kowsari, Synthesis, characterization and study of band gap variations of vanadium doped indium oxide nanoparticles, Physica B: Condensed Matter, 498, (2016), 27-32