Indirect Determination of Ascorbic Acid by Atomic Absorption Spectroscopy

Journal of Physical Chemistry & Eleectrochemistry

مقاله 4، دوره 4، شماره 1، بهمن و اسفند 2016، صفحه 86-92   

نوع مقاله: Research Paper

نویسندگان

Masoomeh Emadi^{* 1}؛ Mohammad AliZare Zare²؛ Omran Moradlou³؛ Maryam Iranpour⁴

¹Young Researchers and Elite Club, Marvdasht Branch, Islamic Azad University, Marvdasht, Iran

²1Young Researchers and Elite Club, Marvdasht Branch, Islamic Azad University, Marvdasht, Iran

³2Department of Chemistry, College of Sciences, Alzahra University, Tehran, Iran

⁴Department of Science and Research Branch, Islamic Azad University, Fars, Iran

تاریخ دریافت: 06 اردیبهشت 1393،  تاریخ بازنگری: 05 خرداد 1393،  تاریخ پذیرش: 05 تیر 1393 

چکیده

A new and simple method followed by atomic absorption spectrometry has been developed
for indirect determination of ascorbic acid (AA). The proposed method was based on the oxidation
of AA to dehydroascorbic acid with Cu2+cation(200mgL-1)in an ammonium thiocyanatesolution at
pH2.4. AA reduces Cu2+to Cu+followed by the precipitation of Cu+ with SCN-. Then, the excess of
Cu2+in the solution was measured by the atomic absorption spectrometry.The results showed that
AA can be sensitively measured in the linear range of 2.0 to 40.0 mgL-1 with the detection limit of
1.5mgL-1.The relative standard deviation (%RSD) was 0.319 in 7 determination of 2.0 mgL-1 AA.
Finally, the method was successfully used for the determination of AA in tablets containing various
amounts of AA.

کلیدواژه‌ها

Ascorbic acid؛ indirect determination؛ atomic absorption spectroscopy